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实验室关于盐模板辅助制造作为锂离子电池先进阳极材料的最新成果发表在JOURNAL OF ALLOYS AND COMPOUNDS
2023-07-11 14:50  

近日,实验室李欣同学、陈梁老师,成功制备了锚定在2DN掺杂碳纳米片(Co3O2 NDs/NCN)杂化物上的Co3O2纳米点,作LIB的阳极时表现出优异的储锂性能的论文发表在Journal Of Alloys And Compounds。

The design and exploitation of advanced transition metal oxides (TMO)/carbon hybrid anodes remain significant but challenging for the evolution of lithium-ion batteries (LIBs). In this work, Co3O4 nanodots anchored into 2D N-doped carbon nanosheets (Co3O4 NDs/NCN) hybrid is successfully fabricated by a facile salt-template assisted pyrolysis strategy using glucose, Co(NO3)2 center dot 6H2O and NaCl salt template as reaction precursors. The morphology, structure and composition of the resultant Co3O4 NDs/NCN hybrid are sys-tematically investigated, and the effect of salt template on the preparation of products is also deeply ex-plored. It is surprisingly found that the introduction of NaCl template promotes the formation of Co3O4 , which is different from what has been reported previously. In addition, the added NaCl template can be used to regulate the microstructure of Co3O4 NDs/NCN hybrid, which displays unique micromorphology (Co3O4 NDs anchored into 2D NCN), successful N doping in carbon matrix, Co-N-C bond between two components and much increased specific surface area. As a result, this hybrid shows excellent lithium storage performance when used as the anode for LIBs, which can be comparable to those previously re-ported Co3O4/C hybrid anodes. Clearly, this work offers a good reference for the construction of low-cost and high-performance TMO/carbon LIBs anodes.

论文题目:Salt-template assisted fabrication of Co3O4 nanodots anchored into 2D N-doped carbon nanosheets as an advanced anode for lithium-ion batteries.

论文作者Liang Chen,Xin Li,Chenxi Xu,Fujia Wang,Wei Wang,Gangyong Li,Minjie Zhou,Binghong He,Wenyuan Xu,Zhaohui Hou.


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